Mole fraction

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In chemistry, the mole fraction or molar fraction (x_i) is defined as the amount of a constituent (expressed in moles), n_i, divided by the total amount of all constituents in a mixture (also expressed in moles), n_tot:

${\displaystyle x_{i}={\frac {n_{i}}{n_{\mathrm {tot} }}}}$

The sum of all the mole fractions is equal to 1:

${\displaystyle \sum _{i=1}^{N}n_{i}=n_{\mathrm {tot} };\;\sum _{i=1}^{N}x_{i}=1}$

The same concept expressed with a denominator of 100 is the mole percent or molar percentage or molar proportion (mol%).

The mole fraction is also called the amount fraction. It is identical to the number fraction, which is defined as the number of molecules of a constituent N_i divided by the total number of all molecules N_tot. The mole fraction is sometimes denoted by the lowercase Greek letter ? (chi) instead of a Roman x. For mixtures of gases, IUPAC recommends the letter y.

The National Institute of Standards and Technology of the United States prefers the term amount-of-substance fraction over mole fraction because it does not contain the name of the unit mole.

Whereas mole fraction is a ratio of moles to moles, molar concentration is a quotient of moles to volume.

The mole fraction is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and volume fraction (percentage by volume, vol%) are others.

Video Mole fraction

Properties

Mole fraction is used very frequently in the construction of phase diagrams. It has a number of advantages:

• it is not temperature dependent (such as molar concentration) and does not require knowledge of the densities of the phase(s) involved
• a mixture of known mole fraction can be prepared by weighing off the appropriate masses of the constituents
• the measure is symmetric: in the mole fractions x = 0.1 and x = 0.9, the roles of 'solvent' and 'solute' are reversed.
• In a mixture of ideal gases, the mole fraction can be expressed as the ratio of partial pressure to total pressure of the mixture
• In a ternary mixture one can express mole fractions of a component as functions of other components mole fraction and binary mole ratios:

${\displaystyle x_{1}={\frac {1-x_{2}}{1+{\frac {x_{3}}{x_{1}}}}}}$

${\displaystyle x_{3}={\frac {1-x_{2}}{1+{\frac {x_{1}}{x_{3}}}}}}$

Differential quotients can be formed at constant ratios like those above:

${\displaystyle \left({\frac {\partial x_{1}}{\partial x_{2}}}\right)_{\frac {x_{1}}{x_{3}}}=-{\frac {x_{1}}{1-x_{2}}}}$

Maps Mole fraction

Related quantities

Mass fraction

The mass fraction w_i can be calculated using the formula

${\displaystyle w_{i}=x_{i}\cdot {\frac {M_{i}}{M}}}$

where M_i is the molar mass of the component i and M is the average molar mass of the mixture.

Replacing the expression of the molar mass:

${\displaystyle w_{i}=x_{i}\cdot {\frac {M_{i}}{\sum _{i}x_{i}M_{i}}}}$

Molar mixing ratio

The mixing of two pure components can be expressed introducing the amount or molar mixing ratio of them ${\displaystyle r_{n}={\frac {n_{2}}{n_{1}}}}$. Then the mole fractions of the components will be:

${\displaystyle x_{1}={\frac {1}{1+r_{n}}}}$

${\displaystyle x_{2}={\frac {r_{n}}{1+r_{n}}}}$

The amount ratio equals the ratio of mole fractions of components:

${\displaystyle {\frac {n_{2}}{n_{1}}}={\frac {x_{2}}{x_{1}}}}$

due to division of both numerator and denominator by the sum of molar amounts of components. This property has consequences for representations of phase diagrams using, for instance, ternary plots.

Mixing binary mixtures with a common component to form ternary mixtures

Mixing binary mixtures with a common component gives a ternary mixture with certain mixing ratios between the three components. These mixing ratios from the ternary and the corresponding mole fractions of the ternary mixture x₁₍₁₂₃₎, x₂₍₁₂₃₎, x₃₍₁₂₃₎ can be expressed as a function of several mixing ratios involved, the mixing ratios between the components of the binary mixtures and the mixing ratio of the binary mixtures to form the ternary one.

${\displaystyle x_{1(123)}={\frac {n_{(12)}x_{1(12)}+n_{13}x_{1(13)}}{n_{(12)}+n_{(13)}}}}$

Mole percentage

Multiplying mole fraction by 100 gives the mole percentage, also referred as amount/amount percent (abbreviated as n/n%).

Mass concentration

The conversion to and from mass concentration ?_i is given by:

${\displaystyle x_{i}={\frac {\rho _{i}}{\rho }}\cdot {\frac {M}{M_{i}}}}$

where M is the average molar mass of the mixture.

${\displaystyle \rho _{i}=x_{i}\rho \cdot {\frac {M_{i}}{M}}}$

Molar concentration

The conversion to molar concentration c_i is given by:

${\displaystyle c_{i}={\frac {x_{i}\cdot \rho }{M}}=x_{i}c}$

or

${\displaystyle c_{i}={\frac {x_{i}\cdot \rho }{\sum _{i}x_{i}M_{i}}}}$

where M is the average molar mass of the solution, c is the total molar concentration and ? is the density of the solution.

Mass and molar mass

The mole fraction can be calculated from the masses m_i and molar masses M_i of the components:

${\displaystyle x_{i}={\frac {\frac {m_{i}}{M_{i}}}{\sum _{i}{\frac {m_{i}}{M_{i}}}}}}$

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Spatial variation and gradient

In a spatially non-uniform mixture, the mole fraction gradient triggers the phenomenon of diffusion.

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References

Source of the article : Wikipedia